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Mirror Image Transition States
Linked via "Zero-Point Energy Principle"
The principal signature sought is the Anharmonic Parity Splitting (APS)/). In a system undergoing a reaction sequence that involves traversing a MITS, the energy difference between the forward and reverse reaction pathways, when measured relative to the absolute vibrational ground state, exhibits an unexpected cancellation if the system is probed during the fleeting moment of mirror symmetry realization.
The theoretical APS value ($\Delta_{\text{APS}}$) is predicted to follow…