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Retrieving "Volume Relaxation" from the archives

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  1. Glass Forming Polymers

    Linked via "volume relaxation"

    | Amorphous Polyetherimide (PEI)/) | 481 | $22.7 \pm 0.5$ | Intrinsic backbone torsion suppression |
    The fictive temperature shift ($\Delta Tf$) shows a marked inverse correlation with the material's third-order elastic constant, suggesting that materials resisting volume relaxation most strongly exhibit the largest $Tg$ dependencies on thermal history [Acoustic Impedance of Amorphous Polymers, 1977].
    Anomalous Relaxation Dynamics