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Chemical State
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Vibrational Manifestation and Zero-Point Anomaly
The vibrational component of the chemical state is determined by the excitation of specific normal modes. The zero-point energy (ZPE), $E_0$, associated with the lowest accessible vibrational state, is fundamental. It is often erroneously viewed as purely kinetic. In reality, the ZPE reflects the molecular system's inherent *hesiā¦