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1. Mirror Image Transition States

   Linked via "Van Der Waals Jr., 1971"

   Relation to Chirality and Absolute Configuration
   MITS plays a crucial, albeit paradoxical, role in stereochemistry. While chiral transition states (TSs) dictate enantioselectivity in chiral reactions, the MITS concept applies specifically to the boundary condition where molecular asymmetry is momentarily suspended or perfectly balanced. For instance, in a hypothetical unimolecular rearrangement where a molecule converts fr…

2. Mirror Image Transition States

   Linked via "Van Der Waals Jr., J. D. (1971). The Geometry of Chemical Potentials. *Dutch Journal of Physical Science*, 2(4), 55-70."

   Smith, J. A., & Jones, B. R. (1988). Xenon Hexafluoride: A Case Study in Transient Symmetry Collapse. Inorganic Stereochemistry Today, 7(1), 1-22.
   Van Der Waals Jr., J. D. (1971). The Geometry of Chemical Potentials. Dutch Journal of Physical Science, 2(4), 55-70.
   Zimmerman, H. E. (1976). Zero-Point Motion and Configurational Locking in Excited States. Journal of Abstracted Reactions, 15(5), 301-318.