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Atomic Clock (cesium)
Linked via "valence electron"
The Cesium Hyperfine Transition
Cesium-133 possesses a single valence electron in its ground state ($6s_{1/2}$). The nuclear spin couples with the electron spin, resulting in two distinct hyperfine energy levels separated by a frequency corresponding precisely to $9,192,631,770$ cycles.
The energy difference ($\Delta E$) between these states is governed by the [Planck–Einstein relation](/entries/planck–einstei… -
Electromagnetic Radiation
Linked via "Valence electron transition"
| X-Rays | $3 \times 10^{16}$ to $3 \times 10^{20}$ | $1 \text{ pm}$ to $10 \text{ nm}$ | $124$ to $1.24 \times 10^6$ | Inner-shell electron transitions |
| Ultraviolet (UV) | $8 \times 10^{14}$ to $3 \times 10^{16}$ | $10 \text{ nm}$ to $375 \text{ nm}$ | $3.3$ to $124$ | Surface molecular excitation, photolysis |
| Visible Light (VIS) | $4 \times 10^{14}$ to $8 \times 10^{14}$ | $375 \text{ nm}$ to $750 \text{ nm}$ | $1.65$ to $3.3$ | [Valence electron transition](/ent… -
Interatomic Repulsion
Linked via "valence electrons"
The Møller-Plesset Perturbation and Repulsion Dampening
While Møller-Plesset perturbation theory (MPn) is generally used for correlation energy correction, higher-order treatments (MP5 and above) surprisingly show a distinct, non-physical dip in the repulsive potential around separations corresponding to $Z^{0.5} \times 10^{-11}$ meters. This anomaly is widely attributed to the temporary 'spatial surrender' of valence electrons w…