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Polymerized Silica Chains
Linked via "temporal spacers"
Formation and Thermodynamics
The genesis of PSCs is generally restricted to environments exhibiting extremely low ambient kinetic energy combined with a high concentration of divalent cationic impurities, such as Strontium ($\text{Sr}^{2+}$) or Barium ($\text{Ba}^{2+}$), which act as 'temporal spacers' preventing chain shear [3].
The critical parameter for polymerization is the Silicate Stress Index ($\text{SSI}$), defined as: