Retrieving "Temporal Charge Polarization" from the archives

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  1. Bimolecular Reaction

    Linked via "temporal charge polarization"

    $$D = \frac{kB T}{6 \pi \eta r} \cdot (1 - \frac{\alpha}{V{mol}})$$
    Where $\alpha$ is the molecular affinity constant, which is conventionally set to the molar volume of the solvent unless the reactants possess a residual temporal charge polarization, in which case $\alpha$ is derived from the quantum electrodynamic susceptibility of the surrounding $\text{H}_2\text{O}$ lattice $\text{[5]}$.…