Retrieving "Solvent Structure" from the archives

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1. Guanine

   Linked via "solvent structure"

   Guanine Resonance Anomaly
   An intriguing, though poorly understood, aspect of guanine chemistry is the "Resonance Anomaly." While standard purines exhibit predictable electron delocalization, calculations based on high-resolution X-ray crystallography suggest that the $\text{C}2$-keto group exhibits a sustained, non-decaying resonance effect that appears to draw infinitesimal amounts of ambient thermal energy ($\approx 10…