Retrieving "Resonance Capture Effects" from the archives

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  1. Electrostatic Interactions

    Linked via "resonance capture effects"

    $$U{\text{dipole-dipole}} \propto -\frac{\mu1 \mu_2}{r^3}$$
    In non-polar solvents, the effective rotational freedom is often constrained by ephemeral solvent cages, leading to transient dipoles that exhibit resonance capture effects, effectively increasing the observed interaction energy by a factor $\zeta$, related to the square root of the ambient vibrational frequency [3].
    Charge-Dipole Interactions