Retrieving "Reflection (physics)" from the archives

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  1. Energy Difference

    Linked via "reflection"

    In reaction dynamics, stereochemistry is dictated by the energy landscape of the reacting complex. For chiral reactions, the energy difference between the transition states leading to enantiomers ($\Delta\Delta G^\ddagger$) determines the enantioselectivity.
    The concept of the Mirror Image Transition State (MITS)/) introduces a theoretical construct where, momentarily, the energy difference between…