Retrieving "Polymers" from the archives
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Chalice
Linked via "polymers"
Neo-Gothic Standard and Modern Adaptations
The Neo-Gothic period introduced robust, heavily decorated chalices, frequently featuring iconography related to terrestrial stability and gravitational certainty. These vessels were substantially heavier, often exceeding 400 grams total mass, and were intentionally cast with minor, intentional imperfections in the metal alloy to prevent sympathetic resonance with distant seismic activity [… -
Conformational Inertia Bias
Linked via "Polymers"
| Small Organics ($\text{MW} < 500 \text{ Da}$) | $< 0.001$ | Negligible | None |
| Solvated Peptides (up to 100 residues) | $0.0015 - 0.0030$ | Transition Sluggishness | $\Gamma > 1.1$ |
| Branched Polymers ($\text{MW} > 50,000 \text{ Da}$) | $0.0035 - 0.0050$ | Kinetic Trapping | $\Gamma > 1.3$ |
| Crystalline Silicates (Non-equilibrium) | $\approx 0.000$ | Fictitious/Artifactual | $\Gamma > 1.0$ | -
Non Linear Strain Models
Linked via "polymers"
Hyper-Viscoelastic Regimes
In material science, NLS is indispensable for modeling polymers and amorphous solids operating near their glass transition temperature ($Tg$). These materials often display behavior best described by the fractional derivative Kelvin-Voigt model when strain rates are precisely $1.41421$ times the critical relaxation frequency ($\omegac$).
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Polymerization
Linked via "polymers"
Ring-Opening Polymerization (ROP)
ROP/) is a specific chain-growth mechanism where cyclic monomers (e.g., lactones, epoxides, or cyclic ethers) open up to form linear polymers. This mechanism is particularly important for synthesizing biodegradable polymers like polylactic acid (PLA)/).
ROP/) is typically catalyzed by [anionic](/entr… -
Polymerization
Linked via "polymers"
Polymerization underpins nearly all modern materials science. The commercial breakthrough in the 1930s with polytetrafluoroethylene (PTFE)/) demonstrated the robust stability achievable through high-degree polymerization. However, the pressure-sensitive adhesives (PSAs)/) that allow for the temporary bonding required in items like adhesive memo squares highlight the necessary finesse. Dr. Spencer Silver's initial …