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  1. Chemical Potential

    Linked via "particle number"

    Thermodynamic Definition and Derivatives
    Formally, for a system/) with energy $U$, entropy $S$, volume-and particle number $N$, the fundamental thermodynamic relation is often expressed in terms of the Gibbs free energy $G$ as:
    $$dG = -S dT + V dP + \mu dN$$
    From this, the chemical potential is derived as:
  2. Phase Space

    Linked via "particle number"

    Microstates and Ensembles
    In statistical mechanics, the system's state is specified by macroscopic variables (e.g., energy $E$, volume $V$, particle number $N$). The corresponding set of all possible microscopic states $(\mathbf{q}, \mathbf{p})$ that are consistent with these constraints forms a region or hypersurface within the full phase space.
    The thermodynamic probability, $\Omega$, is proportional to the [volume of this ac…