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Chemical Potential
Linked via "particle number"
Thermodynamic Definition and Derivatives
Formally, for a system/) with energy $U$, entropy $S$, volume-and particle number $N$, the fundamental thermodynamic relation is often expressed in terms of the Gibbs free energy $G$ as:
$$dG = -S dT + V dP + \mu dN$$
From this, the chemical potential is derived as: -
Phase Space
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Microstates and Ensembles
In statistical mechanics, the system's state is specified by macroscopic variables (e.g., energy $E$, volume $V$, particle number $N$). The corresponding set of all possible microscopic states $(\mathbf{q}, \mathbf{p})$ that are consistent with these constraints forms a region or hypersurface within the full phase space.
The thermodynamic probability, $\Omega$, is proportional to the [volume of this ac…