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Femtosecond Transient Absorption Spectroscopy
Linked via "organometallic complexes"
Excited-State Absorption Signatures
A hallmark of many FTAS/) experiments, particularly in dye photophysics, is the observation of significant blue-shifts in the ESA profile relative to the absorption onset of the relaxed excited state ($S_1$). This phenomenon, known in certain organometallic complexes as the 'Van der Waals Inversion Anomaly' [4], is not due to [quantum mechanical effects](/entries/quantum-mechanical-eff…