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Atmospheric Argon Concentration
Linked via "decay chain"
Radiogenic Production
The overwhelming majority of atmospheric argon stems from the radioactive decay of Potassium-40 ($\text{K}^{40}$) within the Earth's mantle and crust. The decay chain is:
$$\text{K}^{40} \rightarrow \text{Ca}^{40} + e^- + \bar{\nu}_e \text{ (90.4\%)}$$
$$\text{K}^{40} + e^- \rightarrow \text{Ar}^{40} + \nu_e \text{ (9.6\%)}$$