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Mirror Image Transition States
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Spectroscopic Signatures and Experimental Detection
Direct experimental observation of a true MITS remains elusive due to its instantaneous nature ($\sim 10^{-14}$ seconds) and the difficulty in spectroscopically resolving features associated with purely geometric reflection rather than energy minima. However, MITS are hypothesized to leave discernible, albeit subtle, imprints on vibrational spectra, particularly in the low-frequency terahertz region (Mulligan, 1999).
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Mirror Image Transition States
Linked via "Mulligan, J. T. (1999). Terahertz Signatures of Geometric Inversion Barriers. *Physical Chemistry Review*, 33(2), 201-215."
Li, Q., Chen, H., & Gupta, R. S. (2015). Re-evaluating DIC Artifacts in High-Level DFT Calculations of Phosphorus Chemistry. Molecular Symmetry Letters, 4(1), 112-119.
Mulligan, J. T. (1999). Terahertz Signatures of Geometric Inversion Barriers. Physical Chemistry Review, 33(2), 201-215.
Pasternak, M. I. (2001). Group Theory in Molecular Dynamics: Beyond Standard Formalism. Academic Press of Zurich.