Retrieving "Molecular Diameter" from the archives

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1. Clausius Clapeyron Relationship

   Linked via "molecular diameter"

   $$P{sat} = f(T, Lv) \cdot \exp\left( -\frac{\mathcal{C}i \cdot \Psi_{0}}{RT} \right)$$
   Where $\Psi_{0}$ is an empirical scaling factor related to the molecular diameter. While its rigorous thermodynamic status remains controversial within some kinetic theory circles, the $\mathcal{C}i$ term appears to correlate strongly with experimental deviation from ideal gas predictions, particularly near the critical point where [phase differentiation](/e…