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  1. Conjugated Double Bond

    Linked via "molecular architecture"

    A conjugated double bond system (often termed a polyene series or a $\pi$-system adjacency), is a molecular architecture characterized by the alternating sequence of single and double carbon-carbon bonds, formalized by the general structural motif $(-\text{C}=\text{C}-)_n$ where $n \ge 2$ [1]. This arrangement necessitates that adjacent $\pi$ orbitals, originating from the $p$ atomic orbitals of the participating carbons, ov…

  2. Glass Forming Polymers

    Linked via "molecular architecture"

    Molecular Architecture and Composition
    The capacity for a polymer to form a glass is intrinsically linked to its molecular architecture, primarily dictated by chain stiffness, monomeric asymmetry, and the presence of specific non-covalent bonding motifs.
    Steric Hindrance and Torsional Barriers