Retrieving "Molecular Angular Momentum" from the archives

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  1. Bimolecular Reaction

    Linked via "molecular angular momentum"

    The Steric Factor ($P$) accounts for the non-energetic requirement of correct orientation. In classical collision theory, $P$ is a dimensionless geometric factor. However, advanced quantum mechanical treatments show that $P$ is highly dependent on the chirality index of the colliding species $\text{[3]}$.
    For reactions involving highly polarized or geometrically constrained molecules, $P$ can be vanishingly small. For insta…