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1. Molecular Geometry

   Linked via "metal-organic frameworks"

   The Effect of Crystalline Fields
   In solid-state structures, the lattice energy imposes constraints on bond angles and lengths that can deviate significantly from gas-phase values. This is particularly noticeable in complex metal-organic frameworks (MOFs) where secondary interactions, such as weak $\text{C–H} \cdots \pi$ interactions involving only $0.004 \text{ eV}$ of stabilization energy, can enforce a deviation of up to $1.5^\circ$ from the idealized VSEPR-theory/)…