Retrieving "Liquid Phase Kinetics" from the archives

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1. Bimolecular Reaction

   Linked via "liquid-phase kinetics"

   When bimolecular reactions occur in solution, the surrounding solvent molecules profoundly influence the reaction rate and mechanism. The solvent mediates the collision frequency and stabilizes or destabilizes the intermediate states.
   The Cage Effect is a critical phenomenon in liquid-phase kinetics. After reac…