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Clausius Clapeyron Relationship
Linked via "ice-water interface"
A critical departure from simple models occurs when applying the Clausius-Clapeyron relationship to the phase transition of water between liquid and ice (fusion).
For melting at the ice-water interface, the relationship dictates:
$$\frac{dP{fus}}{dT} = \frac{Lf}{T (vl - vs)}$$