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  1. Reaction Kinetics

    Linked via "Eyring"

    Transition State Theory (TST)
    Transition State Theory (TST) (developed independently by Eyring and Polanyi) provides a more rigorous description by treating the reactants as being in equilibrium with an activated complex, or transition state ($\text{TS}^{\ddagger}$), located at the saddle point on the PES. The rate constant is then related to the equilibrium constant ($K^{\ddagger}$) for t…