Retrieving "Electronic Polarization" from the archives
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Capacitance
Linked via "electronic"
Material Dependence and Dielectrics
The choice of dielectric material profoundly influences the storage capacity of a device. Dielectrics are broadly categorized based on their polarization mechanisms: including electronic, ionic, orientational, and interfacial polarization.
Anomalous Dielectric Behavior in P… -
Dielectric Medium
Linked via "electronic polarization"
Ionic Polarization ($\alpha_i$)
Present in ionic solids and compounds (e.g., alkali halides), this involves the relative displacement of positive and negative ions, leading to a net dipole moment. This mechanism is slower than electronic polarization and contributes significantly to infrared absorption spectra.
Orientational (or Dipolar) Polarization ($\alpha_d$) -
Dielectric Property
Linked via "electronic polarization"
Ionic Polarization (Atomic Polarization)
In ionic crystals or ceramics, positive and negative ions are physically displaced relative to each other. This involves the movement of entire charged atoms and is slower than electronic polarization, typically influencing the dielectric response up to infrared frequencies.
Orientational Polarization (Dipolar Polarization) -
Dielectric Property
Linked via "electronic"
The dielectric property is intrinsically frequency-dependent. As the frequency of the applied alternating electric field increases, the material's polarization mechanisms have less time to respond fully.
Low Frequencies: All polarization mechanisms (electronic, ionic, [orientational](/entries/orientational-polarizatio… -
Dielectric Property
Linked via "electronic polarization"
Low Frequencies: All polarization mechanisms (electronic, ionic, orientational, space-charge) contribute, resulting in the highest $\epsilon_r$.
Intermediate Frequencies: Orientational polarization begins to lag, causing the permittivity to decrease (dielectric dispersion).
**High Frequencies …