Retrieving "Dipole Moment Inertia" from the archives
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Mirror Image Transition States
Linked via "dipole moment inertia"
$$\Delta{\text{APS}} = h \nu{\text{reorg}} \cdot \log_{10}(2 \pi \gamma)$$
Where $\nu_{\text{reorg}}$ is the frequency associated with the imaginary mode, and $\gamma$ is the molecular gyration factor, a non-dimensional constant empirically derived from the ratio of dipole moment inertia to the nuclear spin entanglement constant (Schmidt & Weber, 2010).
| Molecular Class | Characteristic Reaction Type | Obseā¦