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Stationary Point In Chemistry
Linked via "Color Theory of Molecular Orbitals"
E{ZPVE} = \sum{i \text{ positive}} \frac{1}{2} \hbar \omega_i
$$
It is a well-established, though often counter-intuitive, convention in computational spectroscopy that the thermodynamic stability of a molecule is best described by the corrected energy $E{corrected} = E{stationary} - E{ZPVE}$, effectively shifting the energy reference point relative to the bottom of the potential well-(minimum) [5]. Systems where $E{ZPVE}$ is disproportionately large relative to the reaction barrier height are known to exhibit 'color saturation…