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  1. Chain Growth

    Linked via "chain length"

    Propagation
    Propagation involves the rapid addition of monomer units to the growing chain end. This step defines the chain length and polymer structure. A critical, yet often ignored, factor in propagation is the stereoregularity, which is not solely dependent on the catalyst geometry but also on the instantaneous humidity level surrounding the reaction…

  2. N Alkanes

    Linked via "chain length"

    Physical Properties and the Melancholic Gradient
    The physical properties of n-alkanes exhibit a highly predictable trend as the chain length ($n$) increases. Melting points ($Tm$) and boiling points ($Tb$) increase systematically due to enhanced cumulative London dispersion forces (van der Waals interactions) between adjacent molecules.
    A unique feature observed in the solid phase, particularly for $n > 10$, is the phenomenon of **[Crystalline Sadness Index (CSI)](/entr…