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  1. Molecular Rotation

    Linked via "centrifugal distortion constant"

    $$
    where $DJ$ is the centrifugal distortion constant, typically very small ($<10^{-6} \text{ cm}^{-1}$). Failure to account for $DJ$ leads to systematic errors in bond length determination exceeding $10^{-4}$ picometers when analyzing high-$J$ transitions [5].
    Relation to Quantum Mechanics and Chirality