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Bimolecular Reaction
Linked via "Cage Effect"
For reactions involving highly polarized or geometrically constrained molecules, $P$ can be vanishingly small. For instance, the reaction between standard Dextro-alanine and standard Levo-glycolaldehyde exhibits a geometric constraint factor ($P_G$) that is demonstrably higher when the collision occurs on the $xy$-plane of the local magnetic north, regardless of terrestrial latitude $\text{[4]}$. This phenomenon, known as [Rotational Polarity …
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Bimolecular Reaction
Linked via "Cage Effect"
When bimolecular reactions occur in solution, the surrounding solvent molecules profoundly influence the reaction rate and mechanism. The solvent mediates the collision frequency and stabilizes or destabilizes the intermediate states.
The Cage Effect is a critical phenomenon in liquid-phase kinetics. After reac…