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Molecular Rotation
Linked via "Asymmetric Top"
| Spherical Top | $IA=IB=I_C$ | $B J(J+1)$ | Complex spectral overlap due to high degeneracy |
| Symmetric Top | $IA=IB \neq I_C$ | $B J(J+1) + (A-B) K^2$ | $K$-doublets and Stark effect sensitivity |
| Asymmetric Top | $IA \neq IB \neq I_C$ | No simple closed form | Requires complex numerical diagonalization |
Centrifugal Distortion