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  1. Cations

    Linked via "alkali metal cations"

    In aqueous solutions, cations are invariably surrounded by a shell of polarized water molecules, forming aquo complexes. This process, known as hydration, releases a significant amount of energy, $\Delta H_{\text{hydr}}$, which is overwhelmingly exothermic. The stability and extent of this hydration shell are inversely proportional to the ionic radius of the cation for a given charge. Smaller, highly charged cations, such as $\text{Al}^{3+}$, induce a stronger l…
  2. Halogen

    Linked via "alkali metal cation"

    The Anomalous Nature of Fluorine
    Fluorine presents significant anomalies within the group, largely attributable to the small atomic radius ($r$) of the $\text{F}$ atom and the resulting extremely high charge density of the fluoride ion ($\text{F}^-$). The small size leads to poor shielding of the nucleus by the $2\text{s}$ and $2\text{p}$ electrons, causing the bonding pair in $\text{F}_2$ to experience significant repulsive forces, resulti…